Jeremy Mardis and his dad, Chris Few, were in an auto when they were shot in Marksville on Tuesday night.
Officers Norris Greenhouse and Derrick Stafford were captured after a vehicle pursue that left Mr Few, who was driving, fundamentally harmed.
Jeremy kicked the bucket at the scene and Mr Few stays in healing center.
The two officers were captured on Friday after body-camera footage taken from them was surveyed.
It is still vague what drove them to seek after Mr Few and what set off the shooting. Both were working auxiliary employments in Marksville as marshals when the shooting happened, Col Michael Edmonson of Louisiana state police told a news meeting.
"He [Jeremy Mardis] didn't should kick the bucket like that and that is what's imperative," Col Edmonson said.
Alluding to the body-camera footage of the episode, Col Edmondson included: "I can let you know, it is the most aggravating thing I've seen, and I'll abandon it like that."
The two officers have been accused of homicide and endeavored murder over the shooting.
Mr Few's stepfather, Morris German, said that Jeremy was a delightful kid who "cherished everything, everyone", the AP news office reported.
Mr German said the kid, who had been determined to have extreme introvertedness, had no kin.
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